Numerical simulation of NAPL flow in the subsurface     

L.K. Kuiper  T.K. Illangasekare 《Computational Geosciences》1998,2(3):171-189

A three-dimensional, three-phase numerical model is presented for simulating the movement of immiscible fluids, including nonaqueous-phase liquids (NAPLs), through porous media. The model is designed to simulate soil flume experiments and for practical application to a wide variety of contamination scenarios involving light or dense NAPLs in heterogeneous subsurface systems. The model is derived for the three-phase flow of water, NAPL, and air in porous media. The basic governing equations are based upon the mass conservation of the constitutents within the phases. The descretization chosen to transform the governing equations into the approximating equations, although logically regular, is very general. The approximating equations are a set of simultaneous coupled nonlinear equations which are solved by the Newton-Raphson method. The linear system solutions needed for the Newton-Raphson method are obtained using a matrix of preconditioner/accelerator iterative methods. Because of the special way the governing equations are implemented, the model is capable of simulating many of the phenomena considered necessary for the sucessful simulation of field problems including entry pressure phenomena, entrapment, and preferential flow paths. The model is verified by comparing it with several exact analytic test solutions and three soil flume experiments involving the introduction and movement of light nonaqueous-phase liquid (LNAPL) or dense nonaqueous-phase liquid (DNAPL) in heterogeneous sand containing a watertable. This revised version was published online in August 2006 with corrections to the Cover Date.  相似文献   

重液材料多钨酸钠在青海湖沉积物重力分离中的应用   总被引：1，自引：0，他引：1  

李善营  于炳松  Hailiang DONG  刘英超 《矿物岩石地球化学通报》2008,27(1):69-71

多钨酸钠是一种无毒、易配制、可循环使用、密度高的新型无机重液.本文利用多钨酸钠重液,用离心机重力分离的方法将青海湖沉积物分成低(≤1.9g/cm3)、中(1.2-2.8g/cm3)、高(≥2.8g/cm3)三个密度组分,平均回收率为96.5%.重力分离后的沉积物测试分析发现,有机质主要分布在富粘土矿物的中密度组,揭示了粘土矿物的表面吸附是青海湖底沉积物有机质的主要赋存形式.  相似文献   

数值模拟技术在海坨子油田开发调整研究中的应用     

翟雨阳  刘钦甫  张立德  唐勇  刘振兴 《上海国土资源》2008,(2):47-50

讨论分析数值模拟技术在海坨子油田开发调整研究中的思路和方法,采用美国Landmark公司VIP2003．4版本数值模拟软件包进行模拟研究,通过参数准备,静、动态拟合,模拟出海坨子油田海S9—11井组1—9砂组各小层剩余储量大小及不同阶段流体饱和度分布,结合可视化技术形象描述了海坨子油田剩余油变化规律及潜力区,在此基础上预测不同井网加密方式开发指标,并优选出最佳方案,为海坨子油田下步开发调整提供了重要依据,取得了较好的效果。  相似文献   

Trace Element Partitioning and Accessory Phase Saturation during H2O-Saturated Melting of Basalt with Implications for Subduction Zone Chemical Fluxes   总被引：2，自引：0，他引：2  

Klimm  Kevin; Blundy  Jon D.; Green  Trevor H. 《Journal of Petrology》2008,49(3):523-553

Experimental phase equilibrium and trace element partitioningdata are reported for H₂O-saturated mid-ocean ridge basalt at2·5 GPa, 750–900°C and oxygen fugacities atthe nickel–nickel oxide buffer. Garnet, omphacite andrutile are present at all temperatures. Amphibole and epidotedisappear as residual phases above 800°C; allanite appearsabove 750°C. The Na–Al-rich silicate glass presentin all run products is likely to have quenched from a supercriticalliquid. Trace element analyses of glasses demonstrate the importantcontrol exerted by residual minerals on liquid chemistry. Inaddition to garnet, which controls heavy rare earth elements(HREE) and Sc, and rutile, which controls Ti, Nb and Ta, allanitebuffers the light REE (LREE; La–Sm) contents of liquidsto relatively low levels and preferentially holds back Th relativeto U. In agreement with previous experimental and metamorphicstudies we propose that residual allanite plays a key role inselectively retaining trace elements in the slab during subduction.Experimental data and analyses of allanite-bearing volcanicrocks are used to derive a model for allanite solubility inliquids as a function of pressure, temperature, anhydrous liquidcomposition and LREE content. The large temperature dependenceof allanite solubility is very similar to that previously determinedfor monazite. Our model, fitted to 48 datapoints, retrievesLREE solubility (in ppm) to within a factor of 1· 40over a pressure range of 0–4 GPa, temperature range of700–1200°C and for liquids with anhydrous SiO₂ contentsof 50–84 wt %. This uncertainty in LREE content is equivalentto a temperature uncertainty of only ± 27°C at 1000K, indicating the potential of allanite as a geothermometer.Silicic liquids from either basaltic or sedimentary protolithswill be saturated in allanite except for Ca-poor protolithsor at very high temperatures. For conventional subduction geothermsthe low solubility of LREE (+ Th) in liquids raises questionsabout the mechanism of LREE + Th transport from slab to wedge.It is suggested either that, locally, temperatures experiencedby the slab are high enough to eliminate allanite in the residueor that substantial volumes of H₂O-rich fluids must pass throughthe mantle wedge prior to melting. The solubility of accessoryphases in fluids derived from subducted rocks can provide importantconstraints on subduction zone thermal structure. KEY WORDS: subduction; experimental petrology; allanite; solubility; supercritical liquid; eclogite  相似文献   

碱消解-高效液相色谱-电感耦合等离子体质谱法测定生物样品中的甲基汞和乙基汞   总被引：7，自引：2，他引：5  

杨红霞  刘崴  李冰 《岩矿测试》2008,27(6):405-408

建立了碱消解-高效液相色谱-电感耦合等离子体质谱联用系统测定生物样品中甲基汞(MeHg)与乙基汞(EtHg)的分析方法。为提高灵敏度,选用微流量的PFA雾化器,在优化的检测条件下,MeHg及EtHg检出限可达到0.036μg/L和0.03μg/L;线性范围达到4个数量级,两条工作曲线线性相关系数为1。对1.78μg/L MeHg、1.65μg/L EtHg的混合标准溶液重复测定7次,色谱峰面积的相对标准偏差(RSD)分别为1.79%和1.44%。对标准物质BCR 464(金枪鱼)的分析结果表明,测定值与标准值基本吻合,但略低于标准值;甲基汞和乙基汞的加标回收率分别为85.9%和84.5%。高效液相色谱与质谱联用技术的高灵敏度和低检出限能够满足生物样品中汞形态定量分析的要求。  相似文献   

渤海湾盆地新生界生油岩系底界面温度分布   总被引：3，自引：1，他引：2       下载免费PDF全文

龚育龄  王良书  刘绍文  李成  韩用兵  李华  蔡进功 《地质科学》2008,43(1):1-11

依据渤海湾盆地2000余口测温井的地温梯度数据、地层岩性描述、分层数据以及钻井资料,计算了该盆地各生油岩系底界面的温度。统计结果表明:渤海湾盆地沙河街组大部分凹陷区地层底界面温度介于90℃至150℃,目前仍具有大量生油的温度条件,而在隆起或一些凸起地区,该地层组段温度普遍小于90℃,未能达到生油的温度指标。东营组和孔店组地层也仍具有一定的生油温度条件。研究还表明:地层温度与地层界面埋深密切相关,温度随界面埋深的增大而升高,沉积厚度大的凹陷区地层界面温度大于沉积厚度小的凸起区或斜坡地带,说明地层界面埋深是决定地温高低的主要控制因素,而地温梯度对地层界面温度的影响相对较小。  相似文献   

水平螺旋槽管壁面液膜传热特性的研究   总被引：2，自引：0，他引：2  

武雅洁  梅宁  李艳 《中国海洋大学学报(自然科学版)》2005,35(1):167-172

对管式高效传热传质元件的工程应用进行理论探讨，根据水平螺旋槽管壁面液膜的形成机理及传热特性，通过建立单组分流体的物理和数学模型，得到了液膜速度和厚度解析解，并分析了在蒸发、冷凝时水平螺槽管的表面几何形状对液膜厚度分布的影响。结果表明：液膜的厚度主要受表面张力和槽道表面几何形状的影响，在槽道内弯处较厚，而在槽道起始处较薄，冷凝时与蒸发时相比液膜厚度更薄，液膜分布更均匀。相对于光滑直管，水平螺旋槽管壁面液膜具有更均匀的厚度分布，具有更好的传热传质性能。  相似文献   

砷酸根的液—固界面交换吸附研究——pH和Ca(Ⅱ)的影响     

赵卫红  张正斌 《中国海洋大学学报(自然科学版)》1997,(2)

研究ｐＨ和Ｃａ（Ⅱ）对砷酸根在海水与ＮａＣｌ介质中对水合氧化物和粘土矿物上交换吸附的影响：（１）在酸性条件下和海水及ＮａＣｌ介质中，砷酸根在针铁矿上的交换率Ｅ（％）—ｐＨ曲线呈平顶峰型、在δ－ＭｎＯ呈峰型、在粘土上分别呈双峰型和肩峰型。这是砷酸根存在多种形式与固体表面发生离子／配位子交换以及介质中阴离子竞争交换吸附共同作用的结果。（２）在碱性条件下的海水介质中，砷酸根与水合氧化物和粘土矿物的Ｅ（％）—ｐＨ曲线都呈Ｖ型，这是因为生成了具有一定结构的液—固界面三元络合物之故。（３）在ＮａＣｌ介质中，Ｃａ加入起促进作用，再次证明液—固界面三元络合物生成机理与Ｖ型曲线的内在关系  相似文献   

海水中234Th的超低水平液闪谱仪测定   总被引：2，自引：1，他引：2  

李鸿宾  黄奕普  陈敏  刘广山  邱雨生 《台湾海峡》2004,23(2):199-207

本文提出了利用超低水平液闪谱仪测定海水中234Th的方法.海水经氢氧化铁吸附共沉淀富集后,接着用阴离子交换和TBP/煤油萃取进行Th同位素的分离与纯化.对一系列测定条件进行了详细的研究,提出了测定海水中234Th的适宜程序,即在含有234Th和产额示踪剂230Th的纯化后的5mol/dm3HNO3溶液中加入TBP/煤油进行萃取,然后用0.1mol/dm3HNO3反萃取,后者是先用契伦柯夫计数法测量234Th(通过234mPa),后加入闪烁液Hisafe 3用α/β模式测量α放射体230Th.对于α和β放射体液闪谱仪的计数效率分别为100%和55.7%±2.7%.234Th的化学回收率和总探测效率分别为70%～80%和30%～45%.该法测定海水中的234Th快速、简便和高效.  相似文献   

大气气溶胶中若干有机物的含量和季节变化   总被引：2，自引：2，他引：2  

张志强  徐少才  王燕 《中国海洋大学学报(自然科学版)》2005,35(4):661-664,628

研究、探讨青岛近岸大气气溶胶中多芳烃类化合物的浓度水平、变化特征及影响因素。用高效液相色谱荧光检测法分析了青岛近岸大气气溶胶中的多环芳烃(PAHs)的含量水平,共检出13种多环芳烃化合物。结果表明该类化合物总量(∑PAHs)具有明显的季节特征,呈现春季<秋季<冬季的特征,人类活动可能是其主要来源。  相似文献